Hydrogeochemical Characterization and Health Risk Assessment of Groundwater Around Dangote Cement Factory, Gboko LGA, Benue State, Nigeria
DOI:
https://doi.org/10.70882/josrar.2026.v3i4.217Keywords:
Groundwater, Hydrogeochemistry, Contamination, Heavy metals, RiskAbstract
Groundwater is a critical domestic water source in peri‑urban Nigeria, yet its quality is increasingly threatened by industrial activities such as cement production. Emissions, dust fall, and wastewater from cement plants can alter aquifer chemistry and introduce toxic constituents into shallow wells that many households rely on. Despite this, robust baseline data and systematic monitoring are often lacking, making it difficult to quantify hydrogeochemical changes and associated health risks in communities near large cement factories. This study assessed the hydrogeochemical characterization and health risk assessment of groundwater quality in four proximal communities (Amua, Hon, Yande, Mbaar) around Dangote cement factory in Gboko LGA, Benue State, Nigeria, evaluating physicochemical properties, heavy metal levels, and associated health/environmental risks against WHO and NESREA standards. Stratified random sampling targeted 12 wells (3 per community), analyzed via AAS for heavy metals (Pb, Cd, Cr, Hg, Fe, Ni, Zn) and UV spectrophotometry for physicochemical parameters (pH, EC, TDS, turbidity, DO, hardness, nitrate); ANOVA, Tukey HSD, Pearson correlations, and multiple regression were performed using SPSS. Physicochemical means showed spatial gradients with Hon highest (pH 8.15±0.11, EC 912.30±13.47 µS/cm, TDS 583.70±11.88 mg/L, nitrate 21.38±0.87 mg/L) and Yande lowest (pH 7.68±0.10, EC 768.40±9.66 µS/cm), all p<0.001; strong positive correlations (r>0.88, p<0.01) linked parameters except DO (negative r<-0.87), while regression explained 92.9% variance (R²=0.929, F=50.840, p<0.001). Heavy metals were below limits except Hon Pb (0.0176 mg/L > WHO 0.01) and near-threshold Cd/Ni; strong inter-metal correlations (r=0.926–0.996, p<0.001) and regression (R²=0.837, p<0.001) confirmed common industrial sources. The findings demonstrate proximity-driven contamination from cement effluent, with moderate mineralization, nutrient enrichment, and elevated chronic risks in communities like Hon. Routine monitoring, emission controls, and remediation are recommended to protect groundwater-dependent populations and ensure sustainable resource management in industrial vicinities.
References
Agaku, R. M., Ikyumbur, J. T., Amanyi, M. I., and Onwoke, E. E. (2025). Assessment of Heavy Metals Concentration in Ground Water in Gboko, Nigeria. Nigerian Journal of Physics, 34(1), 122–133. https://doi.org/10.62292/njp.v34i1.2025.390.
Akighirga, A. T., Shomkegh, S. A., Sambe, L. N., and Ishaq, S. M. (2025). Assessment Of Cement Dust Pollution on Forest Soils Around Dangote Cement Factory Gboko, Benue State, Nigeria. Journal of Arid Agriculture, 26(1), 040–047. https://doi.org/10.63659/jaa/vol.26/issue1/006.
Ameh, E. M., Yahaya, A., Umar, A. Y., Ekwoba, L., Adegbe, A., and Dada, I. O. (2022). Physicochemical Parameters and Heavy Metals in Ground Water Around Dangote Cement Factory Obajana Kogi State Nigeria. Nigerian Journal of Environmental Sciences and Technology, 6(2), 331–338. https://doi.org/10.36263/nijest.2022.02.0375.
Ankidawa, B. A., Sunday, U. L., and Vanke, I. (2021). Water quality index and hydrogeochemistry of Otukpo area, Benue State, North Central Nigeria. Journal of Tropical Resources and Sustainable Science (JTRSS), 6(1), 4–14. https://doi.org/10.47253/jtrss.v6i1.719.
Article, R. (2023). Assessment of Groundwater Hydrochemistry Using Multivariate Statistical Analysis Techniques and Aquachem (Piper Trilinear) the Case Study of Wabishable Basin, Ethiopia. Journal of Water Research, 1(2). https://doi.org/10.33140/jwr.01.02.03.
Ayobami, T. M., Awobode H. O. and Anumudu C. I. (2023). Ecological and Health Risk Assessment of Heavy Metal Contamination in Soil and Plants Around a Cement Factory in Ibese, Ogun State, Nigeria. ASRIC Journal on Engineering Sciences, 4(1): 171-182.
Ayotunde, E. O., Okon, E. E., and Oyeleye, O. A. (2015). Assessment of physicochemical parameters of River Ogun, Ogun State, Southwest Nigeria. Journal of Applied Sciences and Environmental Management, 19(3), 421-428.
Balogun-Adeleye, R., Adu, J. T., and Adisa, R. O. (2022). Assessment and Impacts of Metal Recycling on Groundwater Quality in Ogijo, Ogun State, Nigeria. FUOYE Journal of Engineering and Technology, 7(2), 244–248. https://doi.org/10.46792/fuoyejet.v7i2.799.
Benjamin, D. D., Wachukwu, C. K., Easter, G. N., and Ollor, O. A. (2019). Heavy Metals Assessment of Groundwater Contamination around Waste Management Sites in Rivers State, Nigeria. South Asian Journal of Research in Microbiology, 1–7. https://doi.org/10.9734/sajrm/2019/v3i430094
David A.O., Opafola O.T., Akisanya O.O., Olawomo D.O., and Kadir D.A. (2024). Assessment of Groundwater Quality around a Cement Factory in Ewekoro, Ogun State, Southwest Nigeria. NIU Journal of Social Sciences, 10(2): 49-55.
Dayyabu, F., Karkarna, M. Z., Kura, N. U., & Iya, S. F. D. (2025). Multivariate hydrogeochemical assessment of urban groundwater quality in Kano Metropolis, Nigeria. UMYU Scientifica, 4(3), 66–82. https://doi.org/10.56919/2543.007.
Dey, S., Singh, S., Raju, N. J., and Mall, R. (2024). Hydrogeochemical characterization for groundwater quality and risk assessment in part of central gangetic alluvium, India. Groundwater for Sustainable Development, 25, 101108. https://doi.org/10.1016/j.gsd.2024.101108.
Ebrahimi, M., Kazemi, H., Ehteshami, M., and Rockaway, T. D. (2019). Quality Appraisal of Groundwater in Arid Regions Using Probabilistic and Deterministic Approaches. Environmental and Engineering Geoscience, 25(4), 331–344. https://doi.org/10.2113/eeg-2240.
Edet, A. (2012). Groundwater chemistry and quality of Nigeria: A status review. African Journal of Environmental Science and Technology, 5(13). https://doi.org/10.5897/ajestx11.009.
Edet, A., Nganje, T. N., and Teme, S. (2011). Groundwater quality assessment of Akwa Ibom State using principal component analysis and pollution index. Journal of Applied Sciences and Environmental Management, 15(4), 65-75.
Ganiyu, S.A., Bamisebi, O.T., Omole, B.D., Arowolaje B. S., Adeyemi M. A., Khan R.A., Kuforiji H. I. and Khan N. A. (2026). Quality valuation and hydrogeochemical features of groundwater in university campus and its surroundings, south-west Nigeria. Scientific Reports, 16, 12967 https://doi.org/10.1038/s41598-026-41764-0
uang, C., Lee, T., Pan, J. R., and Hon, J. (2007). Operational performance of sludge blanket in clarification: effect of organic matter. Journal of Water Supply: Research and Technology-Aqua, 56(3), 163–169. https://doi.org/10.2166/aqua.2007.102.
Izinyon, O. C., Meindinyo, L. I., and Ilaboya, I. (2019). Studies on the Quality and Vulnerability of Groundwater to Contamination. Information and Knowledge Management, 9(11). https://doi.org/10.7176/ikm/9-11-05.
Knierim, K. J., Kingsbury, J. A., Clark, B. R., and Haugh, C. (2018, January 1). Using Machine Learning to Map Ph and Redox Conditions in the Mississippi Embayment Regional Aquifer System. https://doi.org/10.1130/abs/2018sc-309580
Laniyan, T. and Adewumi A. (2019). Health Risk Assessment of Heavy Metal Pollution in Groundwater Around an Exposed Dumpsite in Southwestern Nigeria. Journal of Health and Pollution. 9. 1-16. 10.5696/2156-9614-9.24.191210.
Mallick, J., Singh, C. K., Almesfer, M. K., Kumar, A., Khan, R. A., Islam, S., and Rahman, A. (2018). Hydro-Geochemical Assessment of Groundwater Quality in Aseer Region, Saudi Arabia. Water, 10(12), 1847. https://doi.org/10.3390/w10121847
National Environmental Standards and Regulations Enforcement Agency (NESREA). (2011). National Environmental (Surface and Groundwater Quality Control) Regulations. Federal Republic of Nigeria. https://nesrea.gov.ng/wp-content/uploads/2021/10/S_I_No-22_NESREA_national-environmental-surface-groundwater-quality-control-regulations-2011.pdf
Nkpoidet, M. M., Udosen, N. I., and Thomas, J. E. (2025). Hydrochemical assessment of groundwater quality using water quality index, irrigation indices, and corrosivity models in a hydrocarbon-impacted coastal aquifer. Discover Geoscience, 3(1). https://doi.org/10.1007/s44288-025-00220-8.
Ojo, J. T., Ojo, O. M., Olabanji, T. O., and Aluko, R. T. (2024). Urbanization impact on groundwater quality of selected rural and urban areas in Ondo State, Nigeria using Water Quality Index. Discover Water, 4(1). https://doi.org/10.1007/s43832-024-00061-5.
Okoye, C. O. B., and Nyiatagher, T. D. (2009). Physico-Chemical Quality Of Shallow Well-Waters In Gboko,Benue State, Nigeria. Bulletin of the Chemical Society of Ethiopia, 23(1). https://doi.org/10.4314/bcse.v23i1.21309.
Oladapo T. O., Sokan-Adeaga A.A., Akin-Brandom T., Sokan-Adeaga M. A. and Sokan-Adeaga E. D. (2023). Assessment of Heavy Metals Contamination in Groundwater and Its Implications for Public Health Education: A Case Study of an Industrial Area in Southwestern Nigeria. In Groundwater - New Advances and Challenges. IntechOpen. https://doi.org/10.5772/intechopen.109575
Oluseyi, T.O., Olayinka, K.O., and Adeleke, I. (2011). Assessment of ground water pollution in the residential areas of Ewekoro and Shagamu due to cement production. African Journal of Environmental Science and Technology, 5, 786-794.
Oluyemi, E. A., Makinde, W. O., and Oladipo, A. A. (2009). Potential groundwater contamination with toxic metals around refuse dumps in some parts of Lagos metropolis, Nigeria. Toxicological and Environmental Chemistry, 91(5), 933–940. https://doi.org/10.1080/02772240802614978.
Onoyima, C. C., Okpanachi, C. B., & Akoji, J. N. (2025). Hydro-geochemical Characterization and Groundwater Quality Assessment of Mariri Aquifer, Kano, Nigeria. Journal of Agriculture and Environment for International Development (JAEID), 119(1), 469–486. https://doi.org/10.36253/jaeid-17814.
Osisanya, W., Agho, F. I., Saleh, S. A., & Etinosa, T. (2022). Hydrogeochemical characterization and quality assessment of groundwater based on water quality index in urban area in SE Nigeria. Research Square. https://doi.org/10.21203/rs.3.rs-2092987/v1
Uddin, M. G., Diganta, M. T. M., Sajib, A. M., Hasan, M. A., Moniruzzaman, M., Rahman, A., Olbert, A. I., and Moniruzzaman, M. (2023). Assessment of hydrogeochemistry in groundwater using water quality index model and indices approaches. Heliyon, 9(9), e19668. https://doi.org/10.1016/j.heliyon.2023.e19668.
Unande, F., Anko, S. O., Adejare, A. A., Tovide, O. O.and Majolagbe A. O. (2026). Impact assessment of cement manufacturing plant on groundwater quality in Ewekoro Community, Ogun State. Global Journal of Earth and Environmental Science Volume 11(1), pages 1-14.
Van Nguyen, L., Nguyen, N. K., Van Hoang, H., Tran, T. Q., and Vu, N. T. (2012). Characteristics of groundwater in karstic region in northeastern Vietnam. Environmental Earth Sciences, 70(2), 501–510. https://doi.org/10.1007/s12665-012-1548-8.
World Health Organization. (2017). Guidelines for drinking-water quality: Fourth edition incorporating the first addendum. Geneva.
Zacchaeus, O. O., Adeyemi, M. B., Azeem Adedeji, A., Adegoke, K. A., Anumah, A. O., Taiwo, A. M., & Ganiyu, S. A. (2020). Effects of industrialization on groundwater quality in Shagamu and Ota industrial areas of Ogun state, Nigeria. Heliyon, 6(7), e04353.https://doi.org/10.1016/j.heliyon.2020.e04353.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Fredrick Terdoo Ivase, Raymond A. Wuana, David Oriabure Ekhuemelo (Author)

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
- Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- NonCommercial — You may not use the material for commercial purposes.
- No additional restrictions — You may not apply legal terms or technological measures that legally restrict others from doing anything the license permits.