Heavy Metal Contamination in Abuni and Adudu Lead and Zinc Mines in Southern Nasarawa State, Nigeria
DOI:
https://doi.org/10.70882/josrar.2025.v2i3.59Keywords:
Contamination, Heavy metals, Mining, Neutron Activation Analysis, Soil SamplesAbstract
Heavy metal pollution of the environment is becoming a significant issue and a major concern due to the negative consequences it has globally. Artisanal mining, the rapidly expanding mining industries, agriculture, the metal industries, inappropriate waste management, and the use of fertilizers and pesticides are all contributing factors to the release of these inorganic pollutants into the land, water, and environment. This study investigated the concentrations of some heavy metals (Al, Cd, Cr, Cu, Fe, Mn, and Zn) in soil samples from Abuni and Adudu lead and zinc mines, Southern Nasarawa State, Nigeria. Two spots were chosen from each of the mining sites, and soil samples were taken at the topsoil, one foot, and two feet above the ground level, respectively, to achieve a fully representative sampling of the area. The soil samples were processed and analyzed for each metal using instrumental neutron activation analysis. The concentrations of the metals were in the order: Cd < Cu < Cr < Mn < Al < Zn < Fe in Abuni mine and Cd < Cu < Cr < Mn < Al < Fe < Zn in Adudu mine. The heavy metals, Al, Cr, and Cu, fall within the recommended limits. The levels of Cd, Fe, Mn, and Zn in Abuni and Adudu mines were higher than the permitted limits of 3 mg/kg, 50,000 mg/kg, 200 mg/kg, and 421 mg/kg, respectively, set by the Food and Agricultural Organization of the United Nations (FAO) and the Nigerian National Environmental Standards and Regulations Enforcement Agency (NESREA) for Nigerian soils. The study revealed that the soil samples from the mines are contaminated with heavy metals, especially Cd, Fe, and Mn, raising serious environmental and health concerns. It is worth noting that the extremely noticeable values for Zn in all the evaluated indices simply confirm its existence in commercial quantities, as both sites are mining zinc metal.
References
Addo, M.A., Alfum, H.A., Botwe, B.O., Gbadago, J.K., Acquah, S.A., Senu, J.K., Adom, T., Coleman, A., Adu, P.S., Mumuni, I.I. (2012). Assessment of water quality and Heavy Metals Levels in Water and Bottom Sediment Samples from Mokwe Lagoon, Accra, Ghana, Research J. of Environ. And Earth Sc 4(2): 119-130. http://maxwellsci.com/JP/abstract.php?
Akoto, R. and Anning, A.K. (2021). Heavy metal enrichment and potential ecological risks from different solid mine wastes at a mine site in Ghana. Environmental Advances 3, 100028. https://doi.org/10.1016/j.envadv.2020.100028
Anas, M.S., Jonah, S.A., Nasiru, R., Garba, N.N., Muhammad, T. (2023). Development of Neutron Activation Analysis (NAA) protocols for NIRR-1 Irradiation and Counting Facilities after conversion to low-enriched uranium (LEU) core. Sci Set J of Physics 2(1). 01-06. www.mkscienceset.com
Asubiojo, O.I., Adebiyi, F.M., Obiajunwa, E.I., and Ajao, J.A. (2012). Elemental Studies of Soil and Food Flour for Risk Assessment of Highway Pollution Using Particle-Induced X-Ray Emission (PIXE) Spectrometry. International Scholarly Research Network ISRN Analytical Chemistry, 2012, 1-9. https://doi:10.5402/2012/594598
Bykowszczenko, N., Baranowska-Bosiacka, I., Bosiacka, B. (2006). Determination of Heavy Metal Concentration in Mosses of Slowinski National Park Using Absorption Spectrometry and Neutron Activation Analysis Methods. Polish Journal of Environmental Studies 15 (1), 41-46. https://ppm.pum.edu.pl/info/article/PUM3b89b2ef40e14da0af84ecf619cef527/
Briffa, J., Sinagra, E. and Bludell, R. (2020). “Heavy metal pollution in the environment and their toxicological effects on humans”. Heliyon, 6 e 04691. https://doi.org/10.1016/j.heliyon.2020.e04691
Chakravarty, M. and Patgiri, A.D. (2009). Metal pollution assessment in sediments of the Dikrong River, NE India. J. Hum. Ecol., 27(11): 63-67. https://doi.org/10.1080/09709274.2009.11906193
Ekaete, A.G., Ibironke, O.K., Olatunde, P.O., Olaoye, O.P. (2015). Heavy Metal Pollutions and Its Associated Ecological Risks in Lagos Lagoon Sediments, South-western Nigeria. American Chemical Science Journal 9(3): 1-13. https://doi.org/10.9734/ACSJ/2015/20334
Elanga, D., Devi, D., Jeyabalakrisnan, H.K., Rajendran, K., Wand, X. (2022). “Agronomic breeding and biotechnological intervention to mitigate heavy metal toxicity problems in Agriculture. Journal of Agriculture and Food Research, 10 e100374. https://doi.org/10.1039?10.106/j.jafr.2022.100374
Food and Agricultural Organization of the United Nations (FAO)/World Health Organization (WHO), “Codex alimentarius Commission. Food additives and contaminants. Joint FAO/WHO Food Standards Programme” www.transpaktrading.com/static/pdf/research/achemistry/introTofertilizers
Ho, H.H., Swennen, R. and Damme, A.V. (2010). Distribution and contamination status of Heavy metals in estuarine sediments near Cua Ong Harbour, Ha long Bay, Vietnam. Geol. Belgicia. 13/1-2: 37-47. https://doi.org/info:doi/.
Hou, S., Yuan, L., Jin, P., Ding, B., Qin, N.a., Li, Li., Liu, X., Wu, Z., Zhao, G., Deng, Y. (2013). A clinical study of the effects of lead poisoning on the intelligence and neurobehavioral abilities of children. Theor. Biol. Med. Model. 10 (1). https://doi.org/10.1186/1742-4682-10-13.
Karkarna, M.Z. and Matazu, M.A. (2021). Evaluation of Heavy metal pollution around Kano municipal waste Dumpsites, Kano State, Nigeria.UJMR 6 (1): 146-152. https://doi.org/10.47430/ujmr.2161.021
Liu, L., Li, W., Song, W., Guo, M. (2018). Remediation techniques for heavy metal contaminated soil: Principles and applicability. Sa. Total Environ. 633, 206-219. https://doi.org/10.1016/j.scitotenv.2018.03.161
National Environmental Standards and Regulations Enforcement Agency (NESREA), “First Eleven Gazetted Regulations Federal Republic of Nigeria Official Gazette” Available from https://www.nesrea.gov.ng/publications-download/laws-regulations/(2021)
Nasir, M.M. and Aliyu R. (2015). Nuclear and Atomic Methods Applied in the Determination of Some Heavy Pollution Elements in Some Soil Samples Around Industrial Locations in Kano-Nigeria. Science World Journal 10 (1). www.scienceworldjournal.org
Nikolaidis, C., Zafiriadis, I., Mathioudakis, V. (2010). Heavy Metal Pollution Associated with an Abandoned Lead-Zinc Mine in the Kirki Region, NE Greece. Bull Environ Contam Toxicol 85, 307- 312. https://doi.org/10.1007/s00128-010-0079-9
Ojiego, B.O., Ilo, O.P., Okolo, J.C., Igborgbor, J.C., Ishaku, T., Abdullahi, S.A., Gadzama, M.K., Bolorunduro, P. (2022). Concentration of heavy metals in soil samples from dumpsites located at Kuje and Kwali area councils, Abuja, Nigeria. J. Mater. Environ. Sci 13(09), 1037-1046. http://www.jmaterenvironsci.com
Opaluwa, O.D., Aremu, M.O., Ogbo, L.O., Abiola, K.A., Odiba, I.E., Abubakar, M.M., Nweze, N.O. (2012). Heavy metal concentrations in soils, plant leaves and crops grown around dump sites in Lafia Metropolis, Nasarawa State, Nigeria 3 (2), 780-784. http://www.pelagiaresearchlibrary.com/advances-in-applied-science/vol3-iss2/AASR-2012-3-2-780-784.pdf
Nyiramigisha, P., Komariah, and Sajidan. (2021). Harmful Impacts of Heavy Metal Contamination in the Soil and Crops Grown Around Dumpsites. https://doi.org/10.7831/ras.9.0_271
Raymond, A.W., Felix, E.O. (2011). Heavy Metals in Contaminated Soils: A Review of Sources, Chemistry, Risks and Best Available Strategies for Remediation. International Scholarly Research Network (ISRN Ecology), Article ID 402647, 20 pages. https://doi.org/10.5402/2011/402647
Saikat, M., Arka, J.C., Abu, M.T., Talha, B.E., Firzan, N., Ameer, K., Abubakr, M.I., Mayeen, U.K., Hamid, O., Fahad, A.A., Jesus, S. (2022). Impact of heavy metals on the environment and human health: Novel therapeutic insight to counter toxicity. Journal of King Saud University-Science 34, 101865. https://doi.org/10.1016/j.jksus.2022.101865
Srikanth, S. and NagaRaju, G.J. (2019). Quantitative Study of Trace Elements in Coal and Coal related Ashes using PIXE. Journal Geological Society of Indian 94, 533-537. https://doi.org/10.1007/s12594-019-1351-1
Parvez, Md.S., Nawshin, S., Sultana, S., Hossain, Md.S., Khan, Md.H.R., Habib, Md.A., Nijhum, Z.T., Khan, R. (2023). Evaluation of Heavy Metal Contamination in Soil Samples around Rampal, Bangladesh. ACS Omega 8, 15990-15999. https://pubs.acs.org/journal/acsodf
Sun, H., Brocato, J., Costa, M. (2015). Oral chromium exposure and toxicity. Curr. Environ. Heal. Rep. 2(3), 295-303.https://doi.org/10.1007/s40572-015-0054-z.
Sundar, S. and Chakravarty, J. (2010). Antimony toxicity. Int. J. Environ. Res. Public Health 7, 4267-4277. https://doi.org/10.3390/ijerph7124267
Veena, B., Radhakrishnan, C.K., Chacko, J. (1997). Heavy metal induced biochemical effects in an estuarine teleost. Indian J. Mar.Sci. 26:74-78. http://nopr.nispr.res.in/handle/123456789/36150
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